Prep the beef: Pat the chuck roast dry and cut into 1½-inch pieces. Season with salt and pepper, then toss with 2 Tbsp. cornstarch until lightly coated.
3 lbs. boneless beef chuck roast, 1 tsp. kosher salt, 1/2 tsp. black pepper, 4 Tbsp. cornstarch
Sear: Heat the oil in a large skillet over medium-high heat. Working in batches so you don't overcrowd the pan, sear the beef for about 1-2 minutes per side Start Timer. You're looking for a deeply browned exterior, not cooked through. Transfer to the slow cooker and add sliced onions on top.
1 Tbsp. avocado oil or olive oil, 1 yellow onion
Make the sauce: Whisk together the soy sauce, beef broth, brown sugar, hoisin, rice vinegar, sesame oil, garlic, ginger, red pepper flakes, and black pepper.
1/2 cup soy sauce, 1/2 cup beef broth, 1/2 cup packed dark brown sugar, 1/4 cup hoisin sauce, 1 Tbsp. rice vinegar, 1 Tbsp. toasted sesame oil, 6 cloves garlic, 1 Tbsp. fresh ginger, 1/2 tsp. crushed red pepper flakes, 1/2 tsp. black pepper
Add the sauce: Pour over the beef and stir gently.
Slow cook: Cover and cook on LOW for 5-7 hours Start Timer or HIGH for 3-4 hours Start Timer, until the beef is very tender. I recommend low and slow for best results. I would start checking earlier if your chuck is cut fairly small. You want it tender enough to easily bite through, but not completely disintegrating.
Thicken: Whisk the remaining 2 Tbsp. cornstarch with a ladle or two of the sauce from the slow cooker. Stir this slurry into the sauce in the slow cooker. Cover and cook on HIGH for about 10-15 minutes Start Timer, or until the sauce is glossy and thickened.
Finish and serve: Stir in about half of the green onions. Taste. If the sauce feels a little too sweet or heavy, add another 1-2 tsp. rice vinegar. Garnish with the remaining green onions and sesame seeds. Serve with jasmine rice, steamed broccoli, and enjoy!
4-6 green onions, 1-2 tsp. rice vinegar, Toasted sesame seeds, Jasmine rice or rice of choice, Steamed broccoli